- gauche effect
- Макаров: гош-эффект
Универсальный англо-русский словарь. Академик.ру. 2011.
gauche effect
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Gauche effect — Main article: alkane stereochemistry The term gauche refers to conformational isomers (conformers) where two vicinal groups are separated by a 60° torsion angle. IUPAC defines groups as gauche if they have a synclinal alignment of groups attached … Wikipedia
Gauche — can refer to many things: * Gauche (Scheme implementation), an implementation of the Scheme programming language. * In stereochemistry, gauche refers a specific conformer. Gauche Effect hinders bond rotation. * A style of Western fencing using… … Wikipedia
Electronic effect — An electronic effect influences the structure, reactivity, or properties of molecule but is neither a traditional bond nor a steric effect. [G. L. Miessler and D. A. Tarr “Inorganic Chemistry” 3rd Ed, Pearson/Prentice Hall publisher, ISBN 0 13… … Wikipedia
Insuffisance ventriculaire gauche — Insuffisance cardiaque Pour les articles homonymes, voir IC. L’insuffisance cardiaque (IC) correspond à un état dans lequel une anomalie de la fonction cardiaque est responsable de l incapacité du myocarde à assurer un débit cardiaque suffisant… … Wikipédia en Français
Anomeric effect — In organic chemistry, the anomeric effect or Edward Lemieux effect is a stereoelectronic effect that describes the tendency of heteroatomic substituents adjacent to a heteroatom within a cyclohexane ring to prefer the axial orientation instead of … Wikipedia
Glucose — This article is about the naturally occurring D form of glucose. For the L form, see L Glucose. D glucose … Wikipedia
Alkane stereochemistry — concerns the stereochemistry of linear alkanes and the linear alkane conformers. The existence of more than one conformation is due to hindered rotation around sp3 hybridised carbon carbon bonds. The smallest molecule with such a chemical bond,… … Wikipedia
List of effects — This is a list of names for observable phenonema that contain the word effect, amplified by reference(s) to their respective fields of study. #*3D audio effect (audio effects)A*Accelerator effect (economics) *Accordion effect (physics) (waves)… … Wikipedia
Hyperconjugation — In organic chemistry, hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non bonding p orbital or antibonding π orbital or filled π orbital, to give an extended… … Wikipedia
Bent bond — Bent bond, also known as banana bond, is a term in organic chemistry that refers to a type of covalent chemical bond with a geometry somewhat reminiscent of a banana. The term itself is a general representation of electron density or… … Wikipedia
Cis–trans isomerism — Cis but 2 ene Trans but 2 ene In organic che … Wikipedia
